Строение и синтез дигалогенодицианоауратных комплексов [Ph3PR][Au(CN)2Hal2], Hal = Cl, R = Me, СH2Ph; Hal = Br, R = цикло-C6H11; Hal = I, R = Ph

Автор: Шевченко Дмитрий Павлович, Хабина Анастасия Евгеньевна

Журнал: Вестник Южно-Уральского государственного университета. Серия: Химия @vestnik-susu-chemistry

Статья в выпуске: 1 т.13, 2021 года.

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Взаимодействием галогенидов органилтрифенилфосфония с дигалогенодицианоауратом калия в воде с последующей перекристаллизацией продукта реакции из ацетонитрила или ДМСО получены ионные комплексы золота(III) [Ph3PMe][Au(CN)2Cl2] (1), [Ph3PCH2Ph][Au(CN)2Cl2] (2), [Ph3PC6H11- цикло ][Au(CN)2Br2] (3) и [Ph4P][Au(CN)2I2] (4), которые структурно охарактеризованы методом рентгеноструктурного анализа (CIF files CCDC № 1901681 (1), 1912903 (2), 1912919 (3), 2048146 (4)). По данным РСА кристаллы 1-4 состоят из центросимметричных плоскоквадратных анионов [Au(CN)2Hal2]- (средние длины связей Au-Hal 2,417(3) Å (1), 2,280(2) Å (2), 2,4203(13) Å (3) и 2,6035(10) Å (4); средние длины связей Au-C 2,06(2) Å (1), 2,010(7) Å (2), 2,009(7) Å (3) и 1,998(6) Å (4)); атомы фосфора в катионах органилтрифенилфосфония имеют слабо искаженную тетраэдрическую координацию (длины связей P-C 1,782(9)-1,806(8) Å (1), 1,788(4)-1,813(5) Å (2), 1,790(5)-1,813(5) Å (3) и 1,793(6)-1,799(5) Å (4)); атомы фосфора в катионах органилтрифенилфосфония имеют слабо искаженную тетраэдрическую координацию. Структурная организация в кристаллах 2-4 обусловлена межионными водородными связями С-H∙∙∙N≡C (C-HPh∙∙∙N≡C 2,56 Å (2); C-HPh∙∙∙N≡C 2,43-2,59 Å, C-Hциклогексил∙∙∙N≡C 2,47 Å (3), C-HPh∙∙∙N≡C 2,63 Å (4)), в то время как в кристаллах 1 значимых межионных контактов не наблюдается.

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Дигалогенодицианоаураты калия, галогениды тетраорганилфосфония, синтез, строение, рентгеноструктурный анализ

Короткий адрес: https://sciup.org/147234248

IDR: 147234248 | DOI: 10.14529/chem210106

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