Investigation of the effect of the amount of additives on the properties of adipic acid esters

Investigation of the effect of the amount of additives on the properties of adipic acid esters

Автор: Mazitova A.K., Vikhareva I.N., Aminova G.K., Timofeev A.A., Buylova E.A., Distanov R.Sh.

Журнал: Nanotechnologies in Construction: A Scientific Internet-Journal @nanobuild-en

Рубрика: Development of new polymer materials

Статья в выпуске: 4 Vol.11, 2019 года.

Бесплатный доступ

Polyvinylchloride (PVC) is the most frequently used polymer for obtaining a wide range of materials for various purposes. The main advantages of the polymer – excellent thermal and electrical insulation properties, high resistance to various aggressive substances, namely: acids, alkalis, various lubricants; lack of taste, smell; low water absorption (0.4–0.6%). The possibility to obtain PVC-plasticates with different characteristics is provided by the introduction of various additives, the bulk of which are plasticizers. Plasticizers based on adipic acid esters give a number of valuable properties to PVC-based compositions. However, the use of plasticizers affects the resistance of compounds to the combustion, therefore, the substances which eliminate this disadvantage are added in the polymer composition. This paper presents the results of a study of the effect of the composition of mixed plasticizers (symmetric and asymmetric adipates of aliphatic alcohols and phosphate of oxypropylated phenol) on the flammability of PVC composition. Primarily symmetric adipate of cyclic aliphatic alcohols and asymmetric adipate of aliphatic alcohols containing cycloalkyl radical have been derived. Then phosphate of oxypropylated phenol has been synthesized. Physical and chemical properties of the synthesized compounds were studied. Mixtures of plasticizers on the basis of the symmetric adipate of cyclic aliphatic alcohols and asymmetric adipate of aliphatic alcohols containing cycloalkyl radical with varying amounts of phosphate of oxypropylated phenol have been composed. The results of tests of PVC compositions containing the obtained mixtures of plasticizers for flammability are presented. Combustibility parameters of cable plasticate samples with the use of developed plasticizers correspond to state standard 5960-72 with changes 3-9. The best results were achieved with the use of asymmetrical adipate of aliphatic alcohols containing cycloalkyl radical and 4% by weight phosphate of oxypropylated phenol. It is shown that small amounts of phosphate oxypropylated phenol are able to reduce flammability, further addition of this plasticizer leads to a deterioration in performance. The developed formulations of PVC plastics are recommended for use in the production of polyvinylchloride cable sheaths.

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Adipate of aliphatic alcohols, combustibility, PVC compounds, plasticizers of polyvinylchloride, phosphate of oxypropylated phenol

Короткий адрес: https://sciup.org/142227477

IDR: 142227477   |   DOI: 10.15828/2075-8545-2019-11-4-437-446

Список литературы Investigation of the effect of the amount of additives on the properties of adipic acid esters

  • Fedorenko N.P., Universalnyi plastik (Polivinilkhlorid) [Universal plastic (Polyvinylchloride)]. Moscow. Science, 1966. 119 p. (In Russian).
  • Maskova A.R., Aminova G.K., Rolnik L.Z., Faizullina G.F., Mazitova A.K. Oxyalkylated alcohols phthalates. Nanotehnologii v stroitel’stve = Nanotechnologies in Construction. 2019, Vol. 11, no. 1, pp. 52–71. DOI: 10.15828/2075-8545-2019-11-1-52-71.
  • Mazitova A.K., Aminova G.K., Maskova A.R., Sabitov I.N., Nedoseko I.V. New polyvinylchloride plasticizers. Nanotehnologii v stroitel’stve = Nanotechnologies in Construction. 2017, Vol. 9, no. 6, pp. 168–180. DOI: 10.15828/2075-8545-2017-9-6-168-180.
  • Mazitova A.K., Aminova G.K., Maskova A.R., Yagafarova G.G., Mazitov R.M. New plasticizers for PVC-compositionsin construction. Nanotehnologii v stroitel’stve = Nanotechnologies in Construction. 2017, Vol. 9, no. 4, pp. 48–63. DOI: 10.15828/2075- 8545-2017-9-4-48-63.
  • Mazitova A.K., Stepanova L.B., Aminova G.F., Maskova A.R. Razrabotka funkcional’nyh dobavok dlja polivinilhloridnyhkompozicij stroitel’nogo naznachenija [Development of functional additives for polyvinylchloride compositions for construction purposes]. Promyshlennoe proizvodstvo i ispol’zovaniejelastomerov [Industrial production and use of elastomers]. 2015. no. 2, pp. 27–31. (In Russian).
  • Mazitova A.K., Aminova G.K., Nafikova R.F., Deberdeev R.Ja. Osnovnye polivinilhloridnye kompozicii stroitel’nogo naznachenija [Main polyvinylchloride compositions for building purposes]. Ufa, 2013. 130 p. (In Russian).
  • Sapaev H.H., Musov I. V., Hashirova S. Yu., Bashorov M. T., Shogenov V.N., Kushkhov H.B., Mikitaev A.K., Zaikov G.Е. Izuchenie vliyaniya razlichnyh plastifikatorov na svojstva polivinilhloridnogo plastikata [Study of the influence of various plasticizers on the properties of polyvinylchloride plasticate]. Vestnik tekhnologicheskogo universiteta [Bulletin of Technological University]. 2015. Tom 18, № 9, pp. 102–105. (In Russian).
  • Khalturinsky N.A., Berlin A.A., Popova T.V. Gorenie polimerov i mekhanizmy dejstviya antipirenov [The burning of polymers and the mechanisms of action of flame retardant substances]. Uspekhi khimii [Chemical success]. 1984. Vol. 53, № 2, pp. 326. (In Russian).
  • Moisa Iu. N. Plast. massy [Plastic]. 1978. no. 9, pp. 33–35. (In Russian).
  • Ottmar L. Kunststoffe. 1971, Bd. 61, no. 1, pp. 40–46.
  • Tashiro M. Polymer Appl. 1971, Vol. 20, no. 5, pp. 273–278.
  • Troitskii I.D. Polivinilkhloridnye plastikaty i ikh primenenie v kabelnoi tekhnike i ikh primenenie v kabelnoi tekhnike [Polyvinylchloride plasticates and their application in cable engineering and their application in cable engineering]. Moscow. Energy, 1978. 152 p. (In Russian).
  • Musov I.V., Vindizheva A.S., Sapaev H.H., Hashirova S.Yu., Ligidov M.H., Mikitaev A.K. Razrabotka ognestojkogo polivinilhloridnogo plastikata [Development of fire-resistant polyvinylchloride plasticate]. Plasticheskie massy [Plastic masses]. 2011. № 10, pp. 34–36. (In Russian).
  • Musov I.V., Vindizheva A.S., Hashirova S.Yu., Sapaev H.H., Mikitaev A.K. Polivinilhloridnyj plastikat s povyshennoj ognestojkost’yu [Polyvinylchloride plasticate with high fire resistance]. Naukoemkie tekhnologii [High technology]. 2012. № 1, pp. 27–30. (In Russian).
  • Berlin A.A., Vol’fson S.A., Oshmyan V.G., Enikolopyan N.S. Principy sozdaniya kompozicionnyh materialov [Principles of creation of composite materials]. Moscow. Chemistry, 1990. 240 p. (In Russian).
  • Mazitova A.K., Maskova A.R., Nafikova R.F., Aminova G.K. Ispol’zovanie dobavok pri poluchenii kabel’nyh plastikatov [The use of additives in the production of cable plastics]. Bashkirskij himicheskij zhurnal [Bashkir chemical journal]. 2017. Tom 24, № 3, pp. 50–53. (In Russian).
  • Rukovodstvo po razrabotke kompozicij na osnove PVH [Guidelines for the development of compositions based on PVC] / Pod red. Grossmana R.F. [Under the General editorship of R.F. Grossmana]. Saint-Petersburg. Scientific basis and technologies, 2009. 608 p. (In Russian).
  • Sheryshev M.A., Tihonov N.N. Proizvodstvo profil’nyh izdelij iz PVH [Production of profile products from PVC]. Saint- Petersburg. Scientific basis and technologies, 2012. 614 p. (In Russian).
  • Mazitova A.K., Nafikova R.F., Aminova G.K. Plastifikatory polivinilhlorida [Plasticizers of polyvinylchloride]. Nauka i jepoha: monografija. Pod obshhej redakciej professora O.I. Kirikova [Science and epoch: monograph. Under the General editorship of Professor O. I. Kirikova]. Moscow; Voronezh, 2011. pp. 277–297. (In Russian).
  • Uilki Ch., Sammers J., Daniels Ch. Polivinilhlorid [Polyvinylchloride]. Saint-Petersburg. Profession, 2007. 728 p. (In Russian).
  • Barshteyn R.S., Kirilovich V.I., Nosovskiy Y.E. Plastifikatory dlja polimerov [Plasticizers for polymers]. Moscow. Chemistry, 1982. 196 p. (In Russian).
  • Tinius K. Plastifikatory [Plasticizers]. Moscow. Chemistry, 1964. 915 p. (In Russian).
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