Calcium soap lubricants

Автор: Alaz Izer, Tugce Nefise Kahyaoglu, Devrim Balkse

Журнал: НБИ технологии @nbi-technologies

Рубрика: Технико-технологические инновации

Статья в выпуске: 1 (10), 2014 года.

Бесплатный доступ

The article studies the properties of calcium stearate (CaSt2) and lubricants produced on its basis. These lubricants were prepared using sodium stearate and calcium chloride by subsidence from aqueous solutions. The CaSt2 and the light fraction of crude oil were mixed together to obtain lubricating substances. The article shows that CaSt2 had the melting temperature of 142.8 C that is higher than the melting temperature of crude oil (128 C). The compositions of obtained lubricants were studied with optical microscopes. The article shows that the sizes of dispersed particles amount to 1.88 mcm and 0.11 mcm for lubricants having 1 % and 2 % CaSt2 concentration, respectively. As a result of wear trials, it was shown that the friction and wear coefficients of crude oil amounted to 0.099 and 1402 nm, respectively. For the lubricant with 1 % CaSt2 concentration, these coefficients were reduced to 0.0730 and 627.61 nm. Lower wear coefficient (540 nm) was obtained for the lubricant with 2 % CaSt2 concentration. The CaSt2 improved the lubricating property of crude oil but did not improve its oxidative and thermal stability.

Еще

Lubricant, calcium stearate, crude oil, friction coefficient, melting temperature

Короткий адрес: https://sciup.org/14968303

IDR: 14968303

Список литературы Calcium soap lubricants

  • Akira Sasaki, Hideo Aoyama, Tomomi Honda, Yoshiro Iwai & C. K. Yong. A Study of the Colors of Contamination in Used Oils. Tribology Transactions, 2014, no. 57, iss.1, pp. 1-10.
  • Alberty R., Silbey R.J. Physical chemistry. New York, Wiley, 1997. 950 p.
  • Felder E., Levrau C., Mantel M., Dinh NGT. Experimental Study of the Lubrication by Soaps in Stainless Steel Wire Drawing. Proceedings of The Institution of Mechanical Engineers. Part J-Journal of Engineering Tribology, 2011, no. 225 (19, J9), pp. 915-923.
  • Gönen M., Öztürk S., Balköse D., Ülkü S. Preparation and Characterization of Calcium Stearate Powders and Films Prepared by Precipitation and Langmuir-Blodgett Techniques. Ind. and Eng. Chem. Res., 2010, no. 49, pp. 1732-1736.
  • Hughes E.C., Harrison M.S. US2995516 A. Cutting Oil Containing Calcium Stearate. 1956.
  • Lu Y., Miller J.D. Carboxyl Stretching Vibrations of Spontaneously Adsorbed and LB_Transferred Calcium Carboxylates as Determined by FTIR Internal Reflection Spectroscopy. J. Colloid and Interface Sci., 2002, no. 256, pp. 41-52.
  • Moreira A.P. D., Souza B.S., Teixeira A.M.R.F. Monitoring of Calcium Stearate Formation by Thermogravimetry. J. Therm. Anal. Calorim., 2009, no. 97, pp. 647-652.
  • Palichev T., Kramis F.S., Petkov P. Operating-Conservation Motor oil with Composite Additives. Oxidation Communications, 2008, no. 31 (1), pp. 223-230.
  • Savrýk A.S., Balköse D., Ülkü S. Synthesis of Zinc Borate by Inverse Emulsion Technique for Lubrication. J. Therm. Anal. Calorim., 2011, no. 104, pp. 605-612.
Еще
Статья научная